包括：论文（34页 16000字）、答辩稿、文献综述、外文翻译
摘 要 橡胶与金属粘合在许多工业领域有着广泛的应用，如汽车制造、军工方面、道路桥梁以及机械制造等。采用橡胶与金属材料复合可以获得更好的强度和耐久性,同时获得减振、耐磨等功能。 橡胶与金属粘合大都采用硫化粘合方式,但当硫化条件下基材不稳定或硫化粘合工艺不易实现时则采用冷粘方式。由于硫化橡胶表面的极性较弱、活性较低,并且存在脱模剂和喷霜物,因此要想把它粘合到强极性的金属表面上就必须对其进行清理和化学处理。传统的化学处理方法是酸处理法,但该法存在许多缺点,例如使被处理的硫化橡胶表面老化产生微裂纹，导致橡胶物理机械性能下降，并且处理工艺复杂、环境污染严重等。 本文研究了在室温下，通过改变橡胶配方以及胶粘剂配方，对多种硫化橡胶进行了粘合。并对试样进行了拉伸强度、剪切强度、等多项测试。通过对实验结果的分析，探讨了胶粘剂的粘合机理以及影响粘接强度的各种因素。 关键词： 橡胶与金属；粘合； 硫化橡胶 Rubber to metal bonding has an extensive application in many industrial fields. For instance car making, war industry, road, bridge and machine-building etc. Adopt rubber to metal bonding can obtain kind intensity and durability, at the same time, reduced the function of shake , wear-resisting etc. The rubber to metal bonding mostly adopt sulphurate bonding. But if under sulphurating condition the bonding layer is unstable, or suppurating craft is difficult to come true，we adopt cold bonding. Because the polarity on the vulcanized rubber surface is weaker, the activation is relatively low, and exist mold separating agent and blooming. It must go on clear up and chemical disposal if you want to bond the vulcanized rubber to strong polarity metal. The traditional chemical disposal method is acid treatment ,but this method have a lot of shortcoming, for example, makes the vulcanized rubber surface aging and produces a lot of cracks, reduces the vulcanized rubber physical performance, and disposal craft complicated, and seriously polluted environment etc. This paper has been studied under the room temperature, through changing the rubber and adhesive prescription, we have bonded many kinds of rubber to metal. And get on multinomial testing to the sample such as tensile strength, shearing strength,. Through an analysis of experimental result ,we have discussed the bonding mechanism of the adhesive, and the influencing factors of bonding intensity. Key words: rubber and metal; bonding; vulcanized rubber 目 录 参 考 文 献 [1]李士.粘结过程的配位键力的作用，粘接，1983，4（2）：1-6. [2]李子东.偶联剂在环氧粘合剂中的应用[J].粘合剂,1987:（4）33-45. [3]李昂.粘接与胶粘剂[J].特种橡胶制品,2003,24(6)：56－59. [4]尹仪成.橡胶与金属粘合概述[J].中国胶粘剂,1999,8(1)：38-41. [5]丁立朋.硫化橡胶的表面处理对粘合性能的影响[J].橡胶工业,1997,44 (3)：166-169. [6]郭云亮,张涑戎,李立平.偶联剂的种类和特点及应用[J]. 橡胶工业,2003,50(11)：692-696. [7]郭忠信等著：铝合金结构交接：北京：国防工业出版社，1993：5. [8]杨本意,段先健,李仕华,王跃林.气相法白炭黑的应用技术[J].有机硅材料,2003,17(4) ：28-32. [9]向名,菜燎原,张季冰.胶粘剂基础配方设计[M]. 北京：化学工业出版社,2002:25. [10]马天信，姜波.增韧剂对环氧树脂性能的影响[J] .热固性树脂,2003,18(3) ： 7-9. [11]新声，金属-聚合物粘合体育金属表面氧化物的形态结构，你粘合剂，1986，（4）：31-36 [12]盛本麟.有机硅偶联剂的应用[J].热固性树脂,1993(4)：21-25. [13]橡胶工业词典，化工出版社，1989：369. [14]杨本意,段先健,李仕华,王跃林.气相法白炭黑的应用技术[J].有机硅材料,2003,17(4) ：28-32. [15]许健南.塑料材料[M]. 北京：中国轻工业出版社，2001：360. [16] SENTHIL K. JAYASEELAN and W. J. VAN OOIJ Rubber to metal bonding method 967991 (2001) |
硫化丁腈橡胶与金属的室温粘合性能研究
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